Catalytic Oxidative Dehydrogenation of Hydrocarbons (Part 1)
نویسندگان
چکیده
منابع مشابه
Catalytic oxidative dehydrogenation of propane over Mg–V/Mo oxides
Fifteen distinct MgO–V2O5, MgO–MoO3, MgO–V2O5–MoO3, and V2O5–MoO3 compositions were prepared using sol–gel chemistry and their selectivities and conversions for propane oxidative dehydrogenation (ODH) to propylene were measured. The vanadates were more active than the molybdates at lower temperatures; however, the molybdates exhibited higher selectivities at similar conversions. An increase in ...
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Treatment of 5,8-dihydroxy-1-tetralone (9) with either 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) in refluxing benzene or silver (I) oxide in refluxing 1,4-dioxane afforded juglone (5-hydroxy-1,4-naphthoquinone) (1) in good yield. With manganese dioxide in dioxane the tetralone gave a mixture of juglone and naphthazarin (5,8-dihydroxy-1,4-naphthoquinone) (3), the proportion of naphthazarin...
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A number of known catalysts, which have been proven to be very effective for several hydrogen species, were studied in order to determine their effects on the hydrogen ab/desorption properties of KSiH3. Among all the catalysts used in this work, mesoporous Nb2O5 is found to be quite effective, with a reduction in activation energy from 142 kJ mol(-1) for pristine KSi to 63 kJ mol(-1) for mesopo...
متن کاملCatalytic Properties of Supported MoO3 Catalysts for Oxidative Dehydrogenation of Propane
The effects of MoOx structure on propane oxidative dehydrogenation (ODH) rates and selectivity were examined on Al2O3-supported MoOx catalysts with a wide range of surface density (0.4-12 Mo/nm), and compared with those obtained on MoOx/ZrO2. On MoOx/Al2O3 catalysts, propane turnover rate increased with increasing Mo surface density and reached a maximum value for samples with ~ 4.5 Mo/nm. All ...
متن کاملCatalytic dehydrogenation of isopentane with iridium catalysts.
The catalytic activation of alkanes under mild conditions to give the corresponding alkenes and hydrogen has tremendous industrial implications because olefins are the most important starting materials for large-scale industrial processes such as olefin polymerization, dimerization, oligomerization, hydroformylation, and metathesis. In the search for a process by which olefins can be produced f...
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ژورنال
عنوان ژورنال: Journal of The Japan Petroleum Institute
سال: 1968
ISSN: 0582-4664
DOI: 10.1627/jpi1958.11.98